Data sets collectively demonstrate that carbon oxidation state, functional group ratios, and the aggregation kinetics of GO products can be readily controlled by varying processing time and conditions with expected changes in aqueous behavior(s), including stability/aggregation.Yolk-shell silicon/carbon composite encapsulated by uniform carbon shell (Si@C) are becoming an effective method to mitigate volume-related issues of Si-based anodes and maintain an excellent performance for lithium-ion batteries (LIBs). However, a uniform carbon shell in Si@C is difficult to guarantee. Herein, a facile surface-engineering-assisted strategy is described to prepare Si@C composite with low-cost modified recycled waste silicon powders (RWSi) as core coated by a uniform carbon shell-protective layer derived from the pyrolysis of poly (methyl methacrylate) (PMMA) as carbon source (m-RWSi@PMMA-C). In this process, surface-engineering is performed with silane coupling agent kh550 to functionalize the RWSi particles via a silanization reaction, guaranteeing a uniform PMMA coating which will be transformed into carbon shell-protective layer after carbonization. The m-RWSi@PMMA-C electrode delivers an optimal discharge capacity of 1083 mAhg-1 at 200 mAg-1 after 200 cycles with an initial capacity of 3176.2 mAhg-1 and a high initial Coulombic efficiency (ICE) of 75.6%. Based on these results, the recycled silicon-based anode with a uniform carbon shell-protective layer displays great application potential and it also brings a new perspective on silicon-based anodes via surface-engineering method for LIBs.In this work, the porosity, graphitization and iron doping of biochar were realized simultaneously by the pyrolysis of biomass and potassium ferrate (K2FeO4), then the iron-doped graphitized biochar was reduced to synthesize nanoscale zero-valent iron loaded porous graphitized biochar (nZVI/PGBC). 17β-estradiol (E2) is an environmental endocrine disruptor that can cause great harm to the environment in small doses. Experiments illustrated that nZVI/PGBC (100 mg/L) could completely remove E2 (3 mg/L) within 45 min by activating sodium persulfate (PS, 400 mg/L). The E2 removal efficiency of nZVI/PGBC was obviously superior to that of pristine biochar (BC), iron-doped graphitized biochar (Fe/GBC), nanoscale zero-valent iron (nZVI) and porous graphitized biochar (PGBC). The removal efficiency could be affected by reaction conditions, including reaction temperature, acidity, dosage of catalyst and oxidant and water matrix. Quenching experiments and electron spin resonance (ESR) demonstrated that SO4-· and HO were both responsible for E2 degradation. This study indicated that Fe0 and Fe2+ were the main catalytic active substances, while the catalytic ability of PGBC was not obvious. The reaction mechanism was proposed, that is, PS was activated by electrons provided by the redox reaction between Fe2+ and Fe3+, and PGBC acted as the carrier of nZVI, the adsorbent of E2 and the mediator of electron-transfer. This study demonstrates that nZVI/PGBC can be used as an effective activator for PS to remove organic pollutants in water.The aim of this work is, for the first time, to develop new inexpensive, easy-to-make and multi-channel receptors, naphthoquinone-aniline/pyrene union ((Nq-An) and (Nq-Pyr)) and their Hg2+ complexes [Hg-(Nq-An)2] and [Hg-(Nq-Pyr)2] to supply an efficient solution to critical deficiencies to be encountered for Hg2+ recognition. This study is based on colorimetric, fluorometric, and voltammetric methods for determination of Hg2+ ions through Hg-C and Hg-N binding mode of the naphthoquinone-aniline/pyrene union in aqueous media. The binding mode of the receptors with Hg2+ cation was confirmed by usual characterization techniques for the synthesized Hg2+-complexes [Hg-(Nq-An)2] / [Hg-(Nq-Pyr)2] and voltammetric, 1H NMR titration experiments as well as Job's method, indicating a 21 complex between the receptors and Hg2+ cation. The receptors showed a considerable color switching from orange to pink along with a red-shift of absorption wavelength, and fluorescence enhancement via the Chelation Enhanced Fluorescence effect (CHEF), and distinctive changes on the voltammogram of the electroactive naphthoquinone unit with Hg2+ cation. The experiments indicate that the sensors are highly selective and sensitive toward Hg2+ among the studied metal ions in aqueous media compared with other reported Hg2+ sensors.Wastewater treatment plants (WWTPs) associated bioaerosols have emerged as one of the critical sustainability indicators, ensuring health and well-being of societies and cities. In this context, this review summarizes the various wastewater treatment technologies which have been studied with a focus of bioaerosols emissions, potential emission stages, available sampling strategies, survival and dispersion factors, dominant microbial species in bioaerosols, and possible control approaches. Literature review revealed that most of the studies were devoted to sampling, enumerating and identifying cultivable microbial species of bioaerosols, as well as measuring their concentrations. However, the role of treatment technologies and their operational factors are investigated in limited studies only. Moreover, few studies have been reported to investigate the presence and concentrations of air borne virus and fungi in WWTP, as compared to bacterial species.  https://www.selleckchem.com/products/alpha-conotoxin-gi.html  The common environmental factors, affecting the survival and dispersion of bioaerosols, are observed as relative humidity, temperature, wind speed, and solar illumination. Further, research studies on recent episodes of COVID-19 (SARS-CoV-2 virus) pandemic also revealed that continuous and effective surveillance on WWTPs associated bioaerosols may led to early sign for future pandemics. The evaluation of reported data is bit complicated, due to the variation in sampling approaches, ambient conditions, and site activities of each study. Therefore, such studies need a standardized methodology and improved guidance to help informed future policies, contextual research, and support a robust health-based risk assessment process. Based on this review, an integrated sampling and analysis framework is suggested for future WWTPs to ensure their sustainability at social and/or health associated aspects.