Our findings offer a new way to further the development of high-performance energy devices.Two-dimensional (2D) transition metal dichalcogenides (TMDs) such as MoS2 are materials for multifarious applications such as sensing, catalysis, and energy storage. Due to their peculiar charge-transport properties, it is always desired to control their morphologies from vertical nanostructures to horizontal basal-plane oriented smooth layers. In this work, we established a low-temperature ALD process for MoS2 deposition using bis(t-butylimino)bis(dimethylamino)molybdenum(vi) and H2S precursors. The ALD reaction parameters, including reaction temperature and precursor pulse times, are systematically investigated and optimized. Polycrystalline MoS2 is conformally deposited on carbon nanotubes, Si-wafers, and glass substrates. Moreover, the morphologies of the deposited MoS2 films are tuned from smooth film to vertically grown flakes, and to nano-dots, by controlling the reaction parameters/conditions. It is noticed that our MoS2 nanostructures showed morphology-dependent optical and electrocatalytic properties, allowing us to choose the required morphology for a targeted application.Six dimetallic lanthanide complexes, [Ln2(L')(acac)4] (1Dy-3Gd) (Ln = Dy (1Dy), Tb (2Tb) and Gd (3Gd)) and [Ln2(L')(tfac)4] (4Dy-6Gd) (Ln = Dy (4Dy), Tb (5Tb) and Gd (6Gd)) (H2L' = 1,9-dichloro-3,7,11,15-tetraaza-1,9(1,3)-dibenzenacyclohexadecaphane-2,10-diene-1,9-diol), have been synthesized by the reaction of lanthanide nitrates with the HL ligand in the presence of acetylacetonate (acac) (or trifluoroacetylacetonate (tfac) and triethylamine (HL = 4-chloro-2,6-bis(-((3-((3-(dimethylamino)propyl)amino)propyl)imino)methyl)phenol). Ln-Assisted modification of the Schiff base HL occurred and led to the formation of a new macrocyclic ligand (H2L'). X-ray crystallographic analysis revealed that the LnIII ions of complexes 1Dy-6Gd are all eight-coordinated in a square antiprismatic geometry with D4d local symmetry. Magnetic measurements of these complexes revealed that 1Dy and 4Dy show single-molecule magnet behaviour with energy barriers of 66.7 and 79.0 K, respectively, under a zero direct magnetic field. The orientations of the magnetic axes and crystal field parameters were obtained from theoretical calculations and an electrostatic model. The magneto-structural correlations of SMMs 1Dy and 4Dy are further discussed in detail.Herein, a sturgeon skin gelatine film combined with esculin and ferric citrate was developed as an edible food packaging material to prevent Enterococcus faecalis (E. faecalis) contamination. E. faecalis is able to hydrolyse esculin in the film, and then the hydrolysed product, esculetin, combines with ferric citrate to form a brown-black phenol iron complex. This phenomenon can be observed easily after 48 h of contamination under visible light, and it can be determined under 365 nm ultraviolet light with high sensitivity. With the addition of esculin and ferric citrate, the film showed better mechanical properties and water vapour permeability than those of the unmodified gelatine. When an increased amount of esculin was added, an increase in thermal stability, antioxidant activity, and antioxidant stability of the film was observed. These physicochemical characteristics are beneficial for developing a packaging material for food storage that mitigates foodborne illness caused by E. faecalis.The ion-exchange process is usually influenced by the surface properties of the adsorbents. In particular, the prophase adsorption/desorption process is confined by different crystal facets. In this research, spinel Li4Ti5O12 nanosheets with an exposed (1-14) high-index facet were prepared by a hydrothermal method followed by calcination treatment. Then, a H4Ti5O12 adsorbent was obtained, covered with the same (1-14) facets, after treatment with 0.2 M HCl. This special facet-exposed H4Ti5O12 has high cycling ability, with the adsorption uptake remaining at 96.84% after four cycles, a fast adsorption equilibrium time (equilibrium time Mg2+), and good adsorption capacity for Li+ uptake (21.57 mg g-1 ). With the help of X-ray photoelectron spectroscopy analyses, the Li+ adsorption process on the H4Ti5O12 nanosheets is shown to be an ion-exchange process. In addition, the coordination relationship between lithium and oxygen ions was investigated, illustrating that the four-coordinated structure is more stable than other complexes. These results indicate that hydrogen ions are exchanged for lithium ions at tetrahedral 8a sites, leading to the H4Ti5O12 structure with high stability in the adsorption-desorption cycling process.In this work, uniform ultra-small core-shell Au-Pt nanoparticles (denoted as USCS Au-Pt NPs) with Au-decorated Pt surfaces are successfully prepared by Fe(ii)-assisted one-pot co-reduction of Au(iii) ions and Pt(ii) ions in a citrate solution. The as-prepared USCS Au38.4@Au9.3Pt52.3 NPs have an average diameter of 2.3 ± 0.5 nm. It is found that the morphology, composition and size of Au-Pt NPs are highly dependent on the reaction conditions including the addition sequence of the precursors, and the concentrations of Fe(ii) ions, Au(iii) ions and Pt(ii) ions. In addition, USCS Au38.4@Au9.3Pt52.3-NP/C catalysts (USCS Au38.4@Au9.3Pt52.3 NPs loaded on the Vulcan XC-72R carbon black) exhibit excellent electrocatalytic performance towards the hydrogen evolution reaction (HER) and the oxygen reduction reaction (ORR) in acidic media due to the higher electrochemically active surface area (ECSA) and electronic effect between Pt and Au. For instance, USCS Au38.4@Au9.3Pt52.3-NP/C catalysts exhibited greatly enhanced HER activity in terms of overpotential (16 mV at a current density of -10 mA cm-2) and are better than commercial Pt/C catalysts (31 mV at a current density of -10 mA cm-2) reported in the literature thus far, to the best of our knowledge. Strikingly, their mass activity is about 13.1-fold higher than that of commercial Pt/C catalysts. Moreover, they also show an improved ORR activity, Eonset = 1.015 V and E1/2 = 0.896 V, which are positively shifted by nearly 28 mV and 21 mV than those of commercial Pt/C catalysts (0.987 V and 0.875 V), respectively. In addition, they also showed a higher kinetic current density (12.85 mA cm-2 at 0.85 V) and a better long-term durability.  https://www.selleckchem.com/products/hada-hydrochloride.html  Our synthetic strategy presented here may be extended to the preparation of ultra-small Au-based bimetallic or multi-metallic NPs.