Given that there are still some debates on the influence of carbon modification on zerovalent iron (ZVI) decontamination process, the roles of carbon on trichloroethylene (TCE) reduction by ZVI were re-investigated in this work. Compared to activated carbons (AC) with high adsorption ability, carbon fibers (CF) with good electronic conductivity performed much better in enhancing ZVI performance in terms of both reactivity and selectivity. Moreover, it was interesting to observe that a low carbon loading is sufficient to effectively improve TCE reduction and this promoting effect would decline with further increasing the carbon amounts from 1.0 wt.% to 50 wt.%. Regarding to the ZVI selectivity, a relatively high carbon loading (especially for CF, it may be as high as 50 wt.%) was needed to protect ZVI from non-productive reactions with H2O/H+ effectively. However, a mixture of 10 wt.% AC and 1.0 wt.% CF could combine their respective merits of inhibiting side reactions and enhancing TCE reduction, and thus simultaneously enhanced the reactivity and selectivity of ZVI. Mechanistic investigations revealed that carbon modification could enhance the ZVI performance through improving TCE adsorption and/or accelerating electron transfer, while the latter one may play a more important role especially at high carbon loadings. Salt contents and compositions are crucial parameters to enzyme activity and might even affect the proteolysis and quality of dry-cured meat. However, the metal ions significantly vary with geographic origin, which would be a determinant in the dry-cured meat manufacture. Therefore, the main salt compositions of KCl, CaCl2, MgCl2 and ZnCl2 were therefore used to partially substitute NaCl while additionally assessing and regulating their function during the dry-cured pork butts processing. Physiochemical properties, cathepsins activity, proteolysis and sensory evaluation were investigated. The results indicated that partial substitution of sodium prevented the dehydration, and accelerated the pH reduction. CaCl2 and MgCl2 partial substitution moreover exerted some promoting effect on cathepsin activity whereas ZnCl2 was a subtle inhibitor. The proteolysis index of CaCl2 and MgCl2 substitution were superior to the rest. The metal ions partial substitution reduced saltness, while the presence of KCl and MgCl2 enhanced bitterness. Further correlation analysis was performed to better understand the interactions between those parameters. The formation of 4-hydroxy-2-hexenal (HHE) and 4-hydroxy-2-nonenal (HNE) in vegetable oils and model oil systems were quantitatively assessed by RP-HPLC. Regardless of heating temperature, HHE was only detected in rapeseed and linseed oil, while HNE was detected in all tested oils. Intrinsic tocopherols suppressed HHE/HNE formation, but with similar inhibition rates (10.49-16.04%). Linear correlations were observed between HHE/HNE contents and corresponding n-3/6 fatty acid content in oils (R2 = 0.989/0.971). Model oil system revealed that HHE/HNE formation was closely related to methyl linolenate (MLN) and methyl linoleate (ML) contents. Low levels of ML ( less then 0.5%) and MLN ( less then 1.0%) did not lead to HHE/HNE formation.  https://www.selleckchem.com/products/blu-285.html  Therefore, HHE/HNE was classified as the characteristic aldehydes of n-3 and n-6 type oils, respectively. Heat map evaluation and regression analysis indicated HHE could predict the n-3 type oils oxidation, while HNE was a good indicator to estimate the oxidative deterioration of n-6 and n-9 type oils. Based on colloidal gold and broad-spectrum monoclonal antibody that binds to zeranol and its five analogues with high sensitivity, a lateral flow immunochromatographic assay (LFIA) in a competitive format was developed to specifically determine residues of zeranol, an illegal growth promoter in livestock. In this study, the assay had high sensitivity and was broad-spectrum only for zeranol and its five analogues, and the results were obtained within 10 min without needing sophisticated procedures. The cutoff values for zeranol and its five analogues were 10 ng/mL, and the IC50 values for zeranol, β-zearalanol, zearalanone, α-zearalenol, β-zearalenol and zearalenone were 1.250, 1.800, 1.775, 1.225, 1.709 and 1.319 ng/mL, respectively. The recovery rates were ranged from 85.6 to 93.9%, with the coefficient of variations less than 12.4%. The results demonstrated that the LFIA could be used for rapid, simultaneous, semi-quantitative and quantitative detection of residues of zeranol and its five analogous in milk.Red cabbage contains glucosinolates, precursors to health-promoting isothiocyanates. However, raw cabbage often releases mainly epithionitriles and nitriles from glucosinolates. To increase isothiocyanate formation, the effect of acid usage in the preparation of red cabbage was evaluated. Moreover, the effects of the chosen boiling method (acidic boiled red cabbage versus neutral boiled blue cabbage) on glucosinolate degradation were investigated using UHPLC-DAD-ToF-MS and GC-MS. The addition of vinegar significantly increased isothiocyanate formation of cabbage salad from 0.09 to 0.21 µmol/g fresh weight, while lemon juice only slightly increased isothiocyanate formation. Acidic boiled red cabbage degraded glucosinolates and increased nitrile formation, while in neutral boiled blue cabbage, glucosinolates were stable. However, shortly boiled blue cabbage (5 min) had the highest isothiocyanate levels (0.08 µmol/g fresh weight). Thus, for a diet rich in isothiocyanates it is recommended to acidify raw cabbage salads and prepare shortly boiled blue cabbage instead of red cabbage. The current research article was reported the synthesis of a novel poly(3-hydroxy butyrate)-b-poly(vinyl benzyl xanthate) block copolymer (PHB-Xa) for vortex-assisted solid-phase microextraction of cobalt(II) and nickel(II) from canned foodstuffs prior to their determinations by flame atomic absorption spectrometry. The block copolymer was synthesized and characterized by nuclear magnetic resonance spectroscopy and Fourier transform infrared spectroscopy. Experimental variables affecting the extraction efficiency of the copolymer were optimized. Since the PHB-Xa block copolymers have a high π conjugate structure and hydrophobicity, the use of this adsorbent yielded quantitative results for the extraction of Ni(II) and Co(II). After optimization, the linearities for Ni(II) and Co(II) were 0.05-80 ng mL-1 and 0.2-100 ng mL-1, respectively. The limits of detection and the limits of quantification were in the range of 0.015-0.06 ng mL-1 and 0.05-0.2 ng mL-1, respectively. The method was successfully applied to determination of Ni(II) and Co(II) in canned foodstuffs prepared by microwave digestion.