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The 3D spatial structure of dewatered sludge cakes analyzed by computed tomography technology showed that the number of pores of the dewatered sludge cake treated by HACPAM 3 was smaller than that of the cake treated by CPAM, with a reduction in the porosity of 68.8%, resulting in a better hydrophobic effect. In addition, the mechanism of HACPAM improving the dewatering performance is discussed.Flax straw biochar (FSBC)-supported nanoscale zero-valent iron (nZVI) composite (nZVI-FSBC) combining the advantages of nZVI and biochar was synthesized and tested for Cr(VI) removal efficiency from aqueous solution. Surface morphology and structure of FSBC and nZVI-FSBC were characterized by scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and Brunauer-Emmett-Teller techniques, which help to clarify the mechanism of Cr(VI) removal from aqueous solution. The adsorption of Cr(VI) onto FSBC and nZVI-FSBC was best described by the pseudo-second-order and the Sips model. Compared with FSBC, nZVI-FSBC remarkably improved the performance in removing Cr(VI) under identical experimental conditions. Due to the collaborative effect of adsorption and reduction of nZVI-FSBC, the adsorption capacity of nZVI-FSBC for Cr(VI) is up to 186.99 mg/g. The results obtained by XPS, XRD, and FTIR confirmed that adsorption and reduction dominated the processes of Cr(VI) removal by nZVI-FSBC. As a supporter, FSBC not only improved the dispersion of nZVI, but also undertook the adsorption task of Cr(VI) removal. The surface oxygen-containing functional groups of nZVI-FSBC mainly participated in the adsorption part, and the nZVI promoted the Cr(VI) removal through the redox reactions. These observations indicated that the nZVI-FSBC can be considered as potential adsorbents to remove Cr(VI) for environment remediation.Advanced oxidative processes (AOP) have been consolidated as an efficient treatment technique to degrade persistent contaminants. In addition to them, biosorption also emerges as a technique capable of removing both pollutants and intermediate products generated by other treatments such as AOP. Thus, this work evaluated the degradation and removal of the mixture of dyes Direct Red 23 and Direct Red 227 in aqueous solution (50 mg·L-1 of each). Preliminary tests showed that the photo-Fenton system under sunlight radiation was the most efficient, reaching a degradation ≥93%. For the adsorptive process using chicken eggshell, preliminary tests indicated that the ideal dosage of adsorbent was 8.0 g·L-1. For this process, a factorial design indicated the best working conditions, which demonstrated from the system adjusted well to the Elovich (kinetic) model and to the Freundlich and Sips models (equilibrium). When associating the two processes, AOP followed by adsorption achieved a total degradation/removal of ≈98% (for all λ) in a time of 60 min. Thus, the feasibility of the combined treatment is indicated.The Municipality of Asker (Norway) is at risk of not meeting the water quality targets set by the European Union Water Framework Directive within the stipulated timeframe. While there are multiple factors negatively impacting water quality in the municipality, wastewater is likely to be a major contributor. Infiltration and inflow water (I/I-water) leads to a number of unwanted consequences, of which direct discharge of untreated wastewater through overflow points is particularly important. In Aker municipality the portion of I/I-water is about 63%, while the goal is to achieve a level of about 30%. This study utilises a socio-economic cost-effectiveness analysis of measures to prevent sewer overflows into waterbodies. The most effective alternative identified in the analysis is a complete renovation of old pipes in combination with troubleshooting for faulty stormwater connections, when compared to alternatives considering upsizing/retention. I/I-water cost the municipality of Asker NOK34 million in 2017, when using a price of NOK16,434 for each kg of total phosphorus (Tot-P) let into the recipient water bodies. If the phosphorus cost is equal to or less than NOK17,806/kg Tot-P, then it will not be socio-economically justified to reduce I/I-water.Oil leakage from gas stations in Taiwan is commonly caused by the corrosion of oil tanks or loose pipeline joints, contaminating the soil and groundwater near the gas station. Wine-processing waste sludge (WPWS) does not contain toxic substances and has a high organic matter content. Thus, it has high affinity for methyl tert-butyl ether (MTBE) and benzene, toluene, ethylbenzene, and xylenes (BTEX), being suitable for application in preventing and controlling groundwater pollution. In this study, a permeable reaction barrier (PRB) constructed utilizing WPWS in a large water tank was designed to simulate the diffusion and blockage of gasoline plumes in an aquifer. The constructed WPWS PRB had a rectangular shape with a thickness and height of 9 and 60 cm, respectively. The depth in the aquifer was adjusted to 50 cm. MTBE was detected in the aquifer downstream of the WPWS PRB every day during the experiment; however, the maximum concentration detected was only 5.33 ppb. BTEX were only detected on 3 days during the experiment and had maximum concentrations of 1.76, 2.28, 0.34, and 0.60 ppb, which are below the water quality control standards.Melamine foam is an important material in production and life. A series of porous carbon foams were obtained through a simple carbonization process of melamine foam at different temperatures. The carbon foams obtained at the carbonization temperature of 400 and 600 °C reveal a hydrophobic and even super-hydrophobic property (water contact angle larger than 150°) with a hexane adsorption much larger than that of melamine foam. However, the carbon foam obtained at the carbonization temperature of 800 °C reveals a super-hydrophilic property (water contact angle smaller than 5°) due to its severest shrinkage during the carbonization process. https://www.selleckchem.com/products/l-ornithine-l-aspartate.html Interestingly, this series of carbon foams have an excellent performance in oil adsorption. However, the carbon membranes derived from the 800 °C carbon foam reveals oleophobicity under water (the adsorbed water at the surface was extremely important), which allows the penetration of water and blocks the infiltration of hexane at the same time. These different carbon forms have reversed applications in hexane/water separation.
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